The Privileged Pincer Metal Platform Coordination Chemistry Applications

Produk Detail:
  • Author : Gerard van Koten
  • Publisher : Springer
  • Pages : 374 pages
  • ISBN : 3319229273
  • Rating : /5 from reviews
CLICK HERE TO GET THIS BOOK >>>The Privileged Pincer Metal Platform Coordination Chemistry Applications

Download or Read online The Privileged Pincer Metal Platform Coordination Chemistry Applications full in PDF, ePub and kindle. this book written by Gerard van Koten and published by Springer which was released on 27 August 2015 with total page 374 pages. We cannot guarantee that The Privileged Pincer Metal Platform Coordination Chemistry Applications book is available in the library, click Get Book button and read full online book in your kindle, tablet, IPAD, PC or mobile whenever and wherever You Like. The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Organometallic Pincer Chemistry

Organometallic Pincer Chemistry
  • Author : Gerard van Koten,David Milstein
  • Publisher : Springer
  • Release : 17 September 2012
GET THIS BOOK Organometallic Pincer Chemistry

Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and

The Privileged Pincer Metal Platform Coordination Chemistry Applications

The Privileged Pincer Metal Platform  Coordination Chemistry   Applications
  • Author : Gerard van Koten,Robert A Gossage
  • Publisher : Springer
  • Release : 27 August 2015
GET THIS BOOK The Privileged Pincer Metal Platform Coordination Chemistry Applications

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of

Pincer Metal Complexes

Pincer Metal Complexes
  • Author : Akshai Kumar Alape Seetharam
  • Publisher : Elsevier
  • Release : 15 October 2021
GET THIS BOOK Pincer Metal Complexes

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems transforming hydrocarbons and their derivatives from an synthetic and mechanistic point of view. The success stories of pincer-metal systems are discussed, as well as current and future challenges. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also

Pincer Compounds

Pincer Compounds
  • Author : David Morales-Morales
  • Publisher : Elsevier
  • Release : 11 April 2018
GET THIS BOOK Pincer Compounds

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this

Unconventional Pincer Ligands and Their Transition Metal Complexes

Unconventional Pincer Ligands and Their Transition Metal Complexes
  • Author : Caitlin McQueen
  • Publisher : Unknown
  • Release : 17 October 2021
GET THIS BOOK Unconventional Pincer Ligands and Their Transition Metal Complexes

This thesis describes investigations into unconventional pincer systems incorporating non-classical central donor groups. Direct reaction of 1,3-bis(diphenylphosphinomethyl)-2,3-dihydro-1H-1,3,2-benzodiazaborole (dppBH) with metal complexes and subsequent ligand manipulations have provided novel ruthenium and, for the first time, osmium boryl pincer complexes. The boryl complexes thus prepared have been observed to undergo various subsequent reactions involving the chloride and triphenylphosphine co-ligands to give new complexes. Further reactions of dppBH with complexes dichlorotris(triphenylphosphine)ruthenium(II) and -osmium(II) resulted

Synthesis of Bifunctional Pincer Metal Complexes Containing N heterocyclic Carbenes

Synthesis of Bifunctional Pincer Metal Complexes Containing N heterocyclic Carbenes
  • Author : Derek B. Brown
  • Publisher : Unknown
  • Release : 17 October 2021
GET THIS BOOK Synthesis of Bifunctional Pincer Metal Complexes Containing N heterocyclic Carbenes

The goal of this research is to synthesize pincer ligands and complexes with a central pyridine ligand substituted at positions 2 and 6 by two N-heterocyclic carbenes, each bearing a pendant heteroaryl substituent. Related pincers without heteroaryl groups have been reported in the past 15 years as catalysts, and our ultimate goal was to enable the study of the heteroaryl moieties as pendant bases, creating improved bifunctional catalysts. Two classes of pincers were made: one with methylene spacers between the central pyridine and

The Chemistry of Pincer Compounds

The Chemistry of Pincer Compounds
  • Author : David Morales-Morales,Craig G.M. Jensen
  • Publisher : Elsevier
  • Release : 11 August 2011
GET THIS BOOK The Chemistry of Pincer Compounds

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide

Metal Ligand Co operativity

Metal Ligand Co operativity
  • Author : Gerard van Koten,Karl Kirchner,Marc-Etienne Moret
  • Publisher : Springer
  • Release : 30 March 2021
GET THIS BOOK Metal Ligand Co operativity

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands,

Metal ligand Co operativity

Metal ligand Co operativity
  • Author : Anonim
  • Publisher : Unknown
  • Release : 17 October 2021
GET THIS BOOK Metal ligand Co operativity

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of ML co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which

The Development of Next Generation Unsymmetrical CCC NHC Pincer Ligand Architectures and Metalation to Form Unsymmetrical CCC NHC Pincer Ta Complexes

The Development of Next Generation  Unsymmetrical CCC   NHC Pincer Ligand Architectures and Metalation to Form Unsymmetrical CCC   NHC Pincer Ta Complexes
  • Author : Hannah Killian Box
  • Publisher : Unknown
  • Release : 17 October 2021
GET THIS BOOK The Development of Next Generation Unsymmetrical CCC NHC Pincer Ligand Architectures and Metalation to Form Unsymmetrical CCC NHC Pincer Ta Complexes

The impact of N-heterocyclic carbenes (NHC) as ligands for transition metal catalysis has been rigorously investigated since their isolation by Arduengo in 1991. have become abundant in late-transition metal chemistry. This is attributed to NHCs being stronger sigma-donors than even the strongest phosphine analogues, thus constructing a transition metal-NHC complex with improved stability, catalytic reactivity, and selectivity. Additionally, pincer ligands have become recognized as an important class of ligands for transition metal complexes. The unique steric and tunability of pincer ligands

Late Transition metal Complexes Supported by Pincer Ligands

Late Transition metal Complexes Supported by Pincer Ligands
  • Author : Wilson D. Bailey
  • Publisher : Unknown
  • Release : 17 October 2021
GET THIS BOOK Late Transition metal Complexes Supported by Pincer Ligands

Late transition-metal pincer complexes of primarily palladium(II) and platinum(II) have been investigated for their application as catalysts in partial oxidation reactions. The epoxidation of higher olefins using molecular oxygen as the oxidant has been targeted, and the individual reaction steps needed to accomplish this overall transformation are described herein, including: (1) hydrogenolysis of a metal hydroxide (M-OH) species to yield a metal hydride (M-H), (2) insertion of O2 into the M-H bond to form a metal hydroperoxide (M-OOH), and (3) O-atom

Two in one Pincer Type Ligands and Their Metal Complexes for Catalysis

Two in one Pincer Type Ligands and Their Metal Complexes for Catalysis
  • Author : Alexander Gers-Barlag
  • Publisher : Unknown
  • Release : 17 October 2021
GET THIS BOOK Two in one Pincer Type Ligands and Their Metal Complexes for Catalysis

The synthesis, characterization and first applications in catalysis of dinuclear metal complexes of the new Two-in-one pincer ligand scaffold are described in this work. Zinc(II) compexes were used to compare structural and electronical features of two derivatives of the ligand system. Reactivity studies revealed a broad range of reactions for a cobalt(II) complex, although detailed analysis of the reaction products was not possible so far. Furthermore, several rhodium(I) complexes have been synthesized and fully characterized. For a

Metal ligand Co operativity

Metal ligand Co operativity
  • Author : Anonim
  • Publisher : Unknown
  • Release : 17 October 2021
GET THIS BOOK Metal ligand Co operativity

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of ML co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which