Direct Synthesis of Coordination and Organometallic Compounds

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  • Author : A.D. Garnovskii
  • Publisher : Elsevier
  • Pages : 244 pages
  • ISBN : 9780080530444
  • Rating : /5 from reviews
CLICK HERE TO GET THIS BOOK >>>Direct Synthesis of Coordination and Organometallic Compounds

Download or Read online Direct Synthesis of Coordination and Organometallic Compounds full in PDF, ePub and kindle. this book written by A.D. Garnovskii and published by Elsevier which was released on 13 August 1999 with total page 244 pages. We cannot guarantee that Direct Synthesis of Coordination and Organometallic Compounds book is available in the library, click Get Book button and read full online book in your kindle, tablet, IPAD, PC or mobile whenever and wherever You Like. This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of the complex-forming metal), as a result of ligand and metal exchange, and under the conditions of template synthesis, which also include the method of nascent reagents. In these methods the source of the metal is either its salts or carbonyls. At the same time, it has long been known that coordination compounds may be obtained as a result of direct synthesis from zero-valent metals. Methods for the synthesis of complex compounds under the conditions of gas-phase reactions, oxidative dissolution of zero-valent metals in non-aqueous media, and in the solid phase have been developed. These methods have become the basis of a new field in synthetic chemistry - the direct synthesis of coordination and organometallic compounds from zero-valent metals. Particular aspects of the above problem have been described in a series of reviews and monographs. However, on the whole these main parts of the direct synthesis of metal complexes has not been dealt with in the review and monograph publications on coordination chemistry. So, the main objective of this book is to analyze, discuss and generalize the existing information in the area of direct reactions leading to the coordination and organometallic reactions. Some methods of direct synthesis have been developed in the former USSR (in particular, a lot of works on cryosynthesis, pioneered (1972-1973) and recent works on electrosynthesis) but, in spite of their novelty and/or wide applicability, they are practically unknown elsewhere due to the language barrier. Thus, another objective of this book is to acquaint the readers with the mentioned achievements. Every chapter contains the tables which describe all the reported data on direct reaction between metal atoms, metal particles or bulk metals with (in)organic ligans. There are some illustrations also (for example, the scheme of the reactor for gas-phase reaction between metal small particles and &bgr;-diketones).

Direct Synthesis of Coordination and Organometallic Compounds

Direct Synthesis of Coordination and Organometallic Compounds
  • Author : A.D. Garnovskii,B.I. Kharisov
  • Publisher : Elsevier
  • Release : 13 August 1999
GET THIS BOOK Direct Synthesis of Coordination and Organometallic Compounds

This book is devoted to the interaction between elemental metals and (in)organic ligands in different reaction conditions. Metals could be activated for further reactions as cryosynthesis, electrosynthesis and tribosynthesis, some of them with or without ultrasonic and microwave treatment. The kinetics of metal dissolution in various non-aqueous media is discussed in detail. Many methods are used nowadays to synthesize coordination compounds. Metal complexes are obtained mainly by the direct interaction of the components (the ligands and a source of

Direct Synthesis of Metal Complexes

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  • Author : B.I. Kharisov
  • Publisher : Elsevier
  • Release : 19 April 2018
GET THIS BOOK Direct Synthesis of Metal Complexes

Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn’t require organic solvents), with special attention paid to ‘greener’ methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment

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GET THIS BOOK Synthesis of Pesticides Chemical Structure and Biological Activity Natural Products with Biological Activity

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  • Publisher : CRC Press
  • Release : 25 April 2003
GET THIS BOOK Synthetic Coordination and Organometallic Chemistry

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GET THIS BOOK Advances in Organometallic Chemistry

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