Carboranes

📒Carboranes ✍ Russell Grimes

Carboranes Book PDF
✏Book Title : Carboranes
✏Author : Russell Grimes
✏Publisher : Elsevier
✏Release Date : 2012-12-02
✏Pages : 286
✏ISBN : 9780323157582
✏Available Language : English, Spanish, And French

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✏Carboranes Book Summary : Carboranes offers a comprehensive treatment of carborane chemistry and covers topics ranging from structures and chemical bonding to the degradation of the icosahedral cage. Carborane polymers as well as small nido- and closo-carboranes, intermediate closo-carboranes, and o-, m-, and p-carboranes are also discussed. This book is comprised of nine chapters and begins with an overview of the chemistry and properties of carboranes. The discussion then turns to the molecular structures of polyhedral carboranes and open-cage carboranes, along with the isomerism and rearrangement of carboranes; nomenclature and numbering systems used for carboranes; and chemical bonding in boranes and carboranes. The following chapters explore the synthesis, reactions, structures, and properties of small nido- and closo-carboranes, intermediate closo-carboranes, and o-, m-, and p-carboranes. The reactions of boranes and alkylboranes with alkynes as well as the degradation of icosahedral carboranes are also described. This monograph will be a useful resource for organic and inorganic chemists.

📒Carboranes ✍ Russell N. Grimes

Carboranes Book PDF
✏Book Title : Carboranes
✏Author : Russell N. Grimes
✏Publisher : Academic Press
✏Release Date : 2016-12-20
✏Pages : 1058
✏ISBN : 9780128019054
✏Available Language : English, Spanish, And French

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✏Carboranes Book Summary : Carboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic principles underlying the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes. Following the valuable foundational information, the book explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science. These disciplines include polymer science, catalysis, biomedicine, nanomaterials, and others. Includes over 2,000 molecular structure drawings throughout the text Features expanded coverage on applications of carboranes, particularly in biomedicine and nanomaterials, given the growth of research in these areas Presents extended and updated tables, listing thousands of compounds with key literature references, provided online via the book’s website Explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science

Arachno Carboranes Arachno Boranes And The Carbonium Ions C3h7 And C4h7 Nuclear Magnetic Resonance Anomalies Book PDF
✏Book Title : Arachno carboranes Arachno boranes and the Carbonium Ions C3h7 and C4h7 Nuclear Magnetic Resonance Anomalies
✏Author : Robert E. Williams
✏Publisher :
✏Release Date : 1969
✏Pages : 39
✏ISBN : OCLC:227540348
✏Available Language : English, Spanish, And French

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✏Arachno carboranes Arachno boranes and the Carbonium Ions C3h7 and C4h7 Nuclear Magnetic Resonance Anomalies Book Summary : Two sets of hypotheses are presented. The first accounts for the carbon locations among the various position isomers of the carboranes, while the second attempts to cross-correlate most, perhaps all, of the 11B nmr ambiguities thus far reported on the basis of tautomerism involving specific structural elements in selected nido-boranes and all of the arachno-boranes. When taken together the two sets of hypotheses allow us to predict the most probable carbon position isomers among undiscovered and structurally unresolved carboranes and, fulfilling the primary objective of this study, reassures us that major ambiguities should not be anticipated in the spectra of all carboranes which contain two or more carbons. In selected cases the hypotheses can be extended to non-boron containing compounds. Norbornyl cation, for example, has been suggested to have the structure of an arachno-carborane; it possesses the specific structural feature necessary to generate nmr ambiguities, and, indeed, it generates exactly the spectrum for such a tautomerizing system. (Author).

Synthesis Of Carboranes From Dihydrocarboranes  Book PDF
✏Book Title : SYNTHESIS OF CARBORANES FROM DIHYDROCARBORANES
✏Author :
✏Publisher :
✏Release Date : 1963
✏Pages : 16
✏ISBN : OCLC:227313860
✏Available Language : English, Spanish, And French

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✏SYNTHESIS OF CARBORANES FROM DIHYDROCARBORANES Book Summary : Carborane-2,5 is the major volatile carborane formed from the pyrolysis of dihydrocarboranes 2,4. The presence of trimethylamine during the pyrolysis significantly increases the yield of sym-carborane-2,4. The carboranes sym-C2B3H5, unsym-C2B4H6, sym-C2B4H6 and C2B5H7 were prepared in a silent electric discharge in very low yields. It was decided that catalytic removal of H2 or removal of BH3 by a Lewis base might lead to the preparation of C-alkylderivatives of C2B4H6 and C2B3H5, respectively. Since loss of H2 and BH3 are considered to occur in the related boron hydrides merely by heating, a preliminary experi ment was undertaken to determine which reaction was preferred. No alkyl derivatives of C2B3H5 were detected from the dihydrocarboranes. Alkyl derivatives of symmetrical-C2B4H6 were isolated; however, no alkyl derivatives of unsymmetrical C2B4H6 were observed. C-alkyl derivatives of C2B5H7 were produced in unanticipated abundance.

The Use Of Carboranes In Electrolyte Design And Ligand Development Book PDF
✏Book Title : The Use of Carboranes in Electrolyte Design and Ligand Development
✏Author : Scott George McArthur
✏Publisher :
✏Release Date : 2018
✏Pages : 150
✏ISBN : 0438429923
✏Available Language : English, Spanish, And French

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✏The Use of Carboranes in Electrolyte Design and Ligand Development Book Summary : A major part of this work is directed at functionalizing these carborane clusters and incorporating them into imidazolium salts. The imidazoliums bearing functionalized carboranes can then converted into the corresponding N-heterocyclic carbenes (NHC) to be used as ligands for transition metal complexes. This thesis will also contain work in the area of electrolyte development exploiting the weakly coordinating nature of the carborane anion. Both the 10- and 12-vertex carborane clusters can be paired with various cations for their implementation in secondary batteries. Magnesium electrolytes were developed and tested in collaboration with the Guo lab at UC Riverside. Solid-state electrolytes were also developed for various cations and tested by our collaborators at Sandia National Laboratory, Argonne National Laboratory, and the Jet Propulsion Laboratory.

Organometallic Chemistry Book PDF
✏Book Title : Organometallic Chemistry
✏Author : M. Green
✏Publisher : Royal Society of Chemistry
✏Release Date : 2004
✏Pages : 464
✏ISBN : 0854043381
✏Available Language : English, Spanish, And French

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✏Organometallic Chemistry Book Summary : This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

Functionalization Of Carborane Via Carboryne Intermediates Book PDF
✏Book Title : Functionalization of Carborane via Carboryne Intermediates
✏Author : Da Zhao
✏Publisher : Springer
✏Release Date : 2016-06-04
✏Pages : 170
✏ISBN : 9789811015694
✏Available Language : English, Spanish, And French

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✏Functionalization of Carborane via Carboryne Intermediates Book Summary : This thesis focuses on the development of new methods of functionalizing carboranes using o-carboryne intermediates. Functional carboranes are now finding a broad range of applications, including organic synthesis, drug design, polymers, catalysis, metal−organic frameworks, electronic devices and more. However, the limited number of efficient synthetic methods for obtaining functional carborane materials has restricted their applications. The methodologies established in this thesis represent simple, yet powerful strategies to assemble previously inaccessible, useful complex molecules, which will also have a significant impact on future synthetic, cluster and materials chemistry. Moreover, it discusses the first method for the in situ generation of electrophilic boron radical using photocatalysis.

Synthesis And Structure Of Carboranes And Metallacarboranes Book PDF
✏Book Title : Synthesis and Structure of Carboranes and Metallacarboranes
✏Author : David Carl Finster
✏Publisher :
✏Release Date : 1980
✏Pages : 312
✏ISBN : OCLC:8218216
✏Available Language : English, Spanish, And French

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✏Synthesis and Structure of Carboranes and Metallacarboranes Book Summary :

📒B Hydroxy Carboranes ✍ Gary Day Mercer

B Hydroxy Carboranes Book PDF
✏Book Title : B hydroxy Carboranes
✏Author : Gary Day Mercer
✏Publisher :
✏Release Date : 1974
✏Pages : 214
✏ISBN : CORNELL:31924004081703
✏Available Language : English, Spanish, And French

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✏B hydroxy Carboranes Book Summary :

The Synthesis And Characterization Of Some Monocarbon Carboranes And Derivatives Characterization Of The Polynuclear Aromatic Hydrocarbon And Aliphatic Fractions Of Solvent Refined Coal By Capillary Column Gas Chromatography Mass Spectroscopy Book PDF
✏Book Title : The Synthesis and Characterization of Some Monocarbon Carboranes and Derivatives Characterization of the Polynuclear Aromatic Hydrocarbon and Aliphatic Fractions of Solvent Refined Coal by Capillary column Gas Chromatography mass Spectroscopy
✏Author : Rosemary V. Schultz
✏Publisher :
✏Release Date : 1979
✏Pages : 220
✏ISBN : IND:39000002119225
✏Available Language : English, Spanish, And French

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✏The Synthesis and Characterization of Some Monocarbon Carboranes and Derivatives Characterization of the Polynuclear Aromatic Hydrocarbon and Aliphatic Fractions of Solvent Refined Coal by Capillary column Gas Chromatography mass Spectroscopy Book Summary :

Dipole Moments Of Some Carboranes And Of Some Borazines Book PDF
✏Book Title : Dipole Moments of Some Carboranes and of Some Borazines
✏Author : Walter Robert Rysz
✏Publisher :
✏Release Date : 1965
✏Pages : 52
✏ISBN : CORNELL:31924004094631
✏Available Language : English, Spanish, And French

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✏Dipole Moments of Some Carboranes and of Some Borazines Book Summary :

The Condensation Reactions Of The Bis B Hydroxy Carboranes And The Synthetic Reactions Of Metal Atoms With Alkyl Isocyanides Book PDF
✏Book Title : The Condensation Reactions of the Bis B hydroxy Carboranes and the Synthetic Reactions of Metal Atoms with Alkyl Isocyanides
✏Author : Daniel Eugene Gladkowski
✏Publisher :
✏Release Date : 1977
✏Pages : 300
✏ISBN : CORNELL:31924004739755
✏Available Language : English, Spanish, And French

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✏The Condensation Reactions of the Bis B hydroxy Carboranes and the Synthetic Reactions of Metal Atoms with Alkyl Isocyanides Book Summary :

📒Contemporary Boron Chemistry ✍ Matthew G Davidson

Contemporary Boron Chemistry Book PDF
✏Book Title : Contemporary Boron Chemistry
✏Author : Matthew G Davidson
✏Publisher : Royal Society of Chemistry
✏Release Date : 2007-10-31
✏Pages : 552
✏ISBN : 9781847550644
✏Available Language : English, Spanish, And French

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✏Contemporary Boron Chemistry Book Summary : The continued and evolving significance of boron chemistry to the wider chemical community is demonstrated by the international and interdisciplinary nature of the research reported in this book. Contemporary Boron Chemistry encompasses inorganic and organic compounds as well as polymers, solid-state materials, medicinal aspects and theoretical studies. Covering many areas of chemistry with boron at its centre, topics include applications to polyolefin catalysis, medicine, materials and polymers; boron cluster chemistry, including carboranes and metal-containing clusters; organic and inorganic chemistry of species containing only 1 or 2 boron atoms; and theoretical studies of boron-containing compounds. New materials with novel optical and electronic properties are also discussed. Comprehensive and up to date, graduates and researchers in a wide range of fields, particularly those in organometallic and organic chemistry and materials science, will welcome this book.

📒Carboranes ✍ Jess Steven Estrada

Carboranes Book PDF
✏Book Title : Carboranes
✏Author : Jess Steven Estrada
✏Publisher :
✏Release Date : 2017
✏Pages : 108
✏ISBN : 0355471787
✏Available Language : English, Spanish, And French

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✏Carboranes Book Summary : Carborane anions are prized molecules due to their unique structure and bonding, as well as their anomalous stability and resistance to thermal and chemical decomposition. Since their discovery over half a century ago, they have been exploited as weakly coordinating anions stabilizing the most reactive cationic species known, but applications in catalysis by appending carborane anions as ligand substituents had never been attempted. We report a number of carborane-supported zwitterionic and anionic late transition metal complexes to serve as proof of concept for the application of anionic carborane ligand substituents in transition metal catalysis. The results from our studies confirm the anionic carborane is indeed inherently more stable than its isoelectronic neutral cousin, making it a suitable candidate for applications in catalysis. The donor properties of the 12 and 10 vertex anionic carboranes were probed to allow for the possibility of logical tuning of a given transition metal catalyst. Applications in catalysis and studies on the effect of charge as well as the development of a novel N-dicarbollide N-heterocyclic carbene are also reported. The work herein, should mitigate the development of novel single component zwitterionic and anionic transition metal complexes for applications including, but not limited to hydrogenation, dehydrogenation, [alpha]-olefin polymerization, as well as various cross coupling reactions. In addition to the aforementioned, the isolation of the first triazole radical anion is disclosed as well as the methodology to develop a library of potential isolable triazole radical anions for applications in functional materials.

Proton Nmr Study Of The Small Carboranes 1 5 C2b3h5 Cb5h7 1 2 C2b4h6 1 6 C2b4h6 And 2 4 C2b5h7 Book PDF
✏Book Title : Proton Nmr Study of the Small Carboranes 1 5 C2B3H5 CB5H7 1 2 C2B4H6 1 6 C2B4H6 and 2 4 C2B5H7
✏Author : Thomas Onak
✏Publisher :
✏Release Date : 1973
✏Pages : 29
✏ISBN : OCLC:227554068
✏Available Language : English, Spanish, And French

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✏Proton Nmr Study of the Small Carboranes 1 5 C2B3H5 CB5H7 1 2 C2B4H6 1 6 C2B4H6 and 2 4 C2B5H7 Book Summary : Boron-11 decoupled proton nuclear magnetic resonance spectra and data are reported for the closo-carboranes 1,5-C2B3H5, CB5H7, 1,2-C2B4H6, 1,6-C2B4H6, and 2,4-C2B5H7. The proton nmr results are in agreement with the assignments for these carboranes and are compatible with previously obtained boron-11 nmr results. Fine structure, attributed to homonuclear long-range coupling, is observed in the decoupled spectrum of each of these closed polyhedral compounds. An estimate of orbital hybridization in C2B3H5 from coupling data indicates that most of the cage-orbital s-character is to be found in the C-B bonds and very little in the B-B bonds. Chemical shift assignments are made. (Modified author abstract).

Hydrolysis And Methanolysis Of The Small Carboranes 1 5 C2b3h5 1 6 C2b4h6 And 2 4 C2b5h7 The Preparation Of The 1 3 5 Triborapentane Derivatives Ro 2bch2b Or Ch2b Or 2 R Book PDF
✏Book Title : Hydrolysis and Methanolysis of the Small Carboranes 1 5 C2B3H5 1 6 C2B4H6 and 2 4 C2B5H7 The Preparation of the 1 3 5 Triborapentane Derivatives RO 2BCH2B OR CH2B OR 2 R
✏Author : Robert C. Dobbie
✏Publisher :
✏Release Date : 1975
✏Pages : 17
✏ISBN : OCLC:227381733
✏Available Language : English, Spanish, And French

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✏Hydrolysis and Methanolysis of the Small Carboranes 1 5 C2B3H5 1 6 C2B4H6 and 2 4 C2B5H7 The Preparation of the 1 3 5 Triborapentane Derivatives RO 2BCH2B OR CH2B OR 2 R Book Summary : The order of reactivity toward methanol and water for three small close-carboranes is 1,5-C2B3H5> 2,4-C2B5H7> 1,6-C2B4H6. The smallest carborane reacts rapidly with both reagents to form initially the triborapentane, (RO)2BCH2B(OR)CH2B(OR)2 (R = Me, H). The other two carboranes give smaller cleavage products, B(OR)3, MeB(OR)2 and (RO)2BCH2B(OR)2. The mass spectra of both (MeO)2BCH2B(OMe)CH2B(OMe)2 and (MeO)2BCH2B(OMe)2 are discussed.

Carborane 2 Book PDF
✏Book Title : Carborane 2
✏Author :
✏Publisher : Springer
✏Release Date : 1975-10-29
✏Pages : 150
✏ISBN : 3540933018
✏Available Language : English, Spanish, And French

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✏Carborane 2 Book Summary :

📒Index Volume Category 1 ✍ Colin J. Drayton

Index Volume Category 1 Book PDF
✏Book Title : Index Volume Category 1
✏Author : Colin J. Drayton
✏Publisher : Georg Thieme Verlag
✏Release Date : 2014-05-14
✏Pages : 1000
✏ISBN : 9783131784919
✏Available Language : English, Spanish, And French

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✏Index Volume Category 1 Book Summary : Science of Synthesis provides a critical review of the synthetic methodology developed from the early 1800s to date for the entire field of organic and organometallic chemistry. As the only resource providing full-text descriptions of organic transformations and synthetic methods as well as experimental procedures, Science of Synthesis is therefore a unique chemical information tool. Over 1000 world-renowned experts have chosen the most important molecular transformations for a class of organic compounds and elaborated on their scope and limitations. The systematic, logical and consistent organization of the synthetic methods for each functional group enables users to quickly find out which methods are useful for a particular synthesis and which are not. Effective and practical experimental procedures can be implemented quickly and easily in the lab.// The content of this e-book was originally published in November 2007.

📒Boron Hydride Chemistry ✍ Earl Muetterties

Boron Hydride Chemistry Book PDF
✏Book Title : Boron Hydride Chemistry
✏Author : Earl Muetterties
✏Publisher : Elsevier
✏Release Date : 2012-12-02
✏Pages : 544
✏ISBN : 9780323146494
✏Available Language : English, Spanish, And French

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✏Boron Hydride Chemistry Book Summary : Boron Hydride Chemistry covers the significant contributions of boron hydride research in the subjects of bonding, structure, and stereochemistry. This book contains 12 chapters that illustrate the merging of certain areas of boron hydride chemistry with other disciplines, such as organic, organometallic, and transition metal chemistry. After providing an overview of the general geometric, stereochemical, and dynamic stereochemical features of boron hydrides, this book goes on exploring the bonding theory and theoretical research on boron hydrides, with an emphasis on boron hydrides that have open polyhedral structures. These topics are followed by discussions on gas phase and solution reactions of borane and substituted boranes. A chapter focuses on the chemistry of cations containing boron atoms bonded to hydrogen. The remaining chapters examine the syntheses, structures, bonding, spectral properties, and chemistry of specific boron hydrides, including borazines, closo-boron hydrides, carboranes, icosahedral carboranes, and close- and nido-heteroboranes. Inorganic chemists and researchers, teachers, and undergraduate inorganic chemistry students will find this book invaluable.

📒Organometallic Chemistry ✍ Royal Society of Chemistry

Organometallic Chemistry Book PDF
✏Book Title : Organometallic Chemistry
✏Author : Royal Society of Chemistry
✏Publisher : Royal Society of Chemistry
✏Release Date : 2001
✏Pages : 550
✏ISBN : 0854043284
✏Available Language : English, Spanish, And French

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✏Organometallic Chemistry Book Summary : This Specialist Periodical Report aims to reflect the growing interest in the potential of organometallic chemistry.

The Borane Carborane Carbocation Continuum Book PDF
✏Book Title : The Borane Carborane Carbocation Continuum
✏Author : Joseph Casanova
✏Publisher : Wiley-Interscience
✏Release Date : 1998-04-29
✏Pages : 437
✏ISBN : STANFORD:36105023075232
✏Available Language : English, Spanish, And French

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✏The Borane Carborane Carbocation Continuum Book Summary : Lipscomb, to illustrate the results of research on the structures and bonding characteristics of boranes, carboranes, and carbocations.

Modern Physical Organic Chemistry Book PDF
✏Book Title : Modern Physical Organic Chemistry
✏Author : Eric V. Anslyn
✏Publisher : University Science Books
✏Release Date : 2006
✏Pages : 1095
✏ISBN : 1891389319
✏Available Language : English, Spanish, And French

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✏Modern Physical Organic Chemistry Book Summary : Making explicit the connections between physical organic chemistry and critical fields such as organometallic chemistry, materials chemistry, bioorganic chemistry and biochemistry, this book escorts the reader into an area that has been thoroughly updated in recent times.

Journal Of General Chemistry Of The U S S R In English Translation Book PDF
✏Book Title : Journal of General Chemistry of the U S S R in English Translation
✏Author :
✏Publisher :
✏Release Date : 1987
✏Pages :
✏ISBN : UCSD:31822017864570
✏Available Language : English, Spanish, And French

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✏Journal of General Chemistry of the U S S R in English Translation Book Summary :

Comprehensive Organometallic Chemistry Iii Book PDF
✏Book Title : Comprehensive organometallic chemistry III
✏Author : D. M. P. Mingos
✏Publisher :
✏Release Date : 2007
✏Pages : 946
✏ISBN : 008044590X
✏Available Language : English, Spanish, And French

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✏Comprehensive organometallic chemistry III Book Summary :

📒Progress In Boron Chemistry ✍ R. J. Brotherton

Progress In Boron Chemistry Book PDF
✏Book Title : Progress in Boron Chemistry
✏Author : R. J. Brotherton
✏Publisher : Elsevier
✏Release Date : 2016-10-12
✏Pages : 310
✏ISBN : 9781483146614
✏Available Language : English, Spanish, And French

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✏Progress in Boron Chemistry Book Summary : Progress in Boron Chemistry, Volume 2 presents the chemistry and applications of boron and its compounds. This book provides a critical treatment of six areas of boron chemistry, including polyhedral borane ions, carboranes, polymers, hydrogen, metal borides, and elemental boron. Organized into six chapters, this volume begins with an overview of the structures as well as the synthesis of polyhedral borane anions. This text then examines the various types of classes and series of the carboranes. Other chapters consider the relatively intramolecular rearrangements and intramolecular exchange reactions concerning the various closo-carboranes and nido-carboranes. This book discusses as well the formation and the historical significance of a higher boron hydride polymer. The final chapter deals with the structural utilization of boron filaments, which promises to be the first large-scale use for comparatively high purity elemental boron. This book is intended to be suitable for boron chemists, chemical engineers, scientists, and research workers.

Annual Reports On Nmr Spectroscopy Book PDF
✏Book Title : Annual Reports on NMR Spectroscopy
✏Author :
✏Publisher : Academic Press
✏Release Date : 1988-05-01
✏Pages : 374
✏ISBN : 0080584039
✏Available Language : English, Spanish, And French

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✏Annual Reports on NMR Spectroscopy Book Summary : Annual Reports on NMR Spectroscopy

The Application Of Carborane Anions In Ligand Design And Materials Development Book PDF
✏Book Title : The Application of Carborane Anions in Ligand Design and Materials Development
✏Author : Sarah Elizabeth Lee
✏Publisher :
✏Release Date : 2018
✏Pages : 195
✏ISBN : 0438430522
✏Available Language : English, Spanish, And French

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✏The Application of Carborane Anions in Ligand Design and Materials Development Book Summary : A large component of this work addresses the incorporation of both the 10 and 12- vertex carborane anions into ligand motifs. Carborane clusters are not typically included in catalyst design, and since the 1960's there have been only a few investigations exploring the applications of carboranes in ligand development. Carboranes are excellent synthons for constructing covalently bonded, architecturally novel molecules whose electronic and steric properties can be tailored to specific purposes. Beyond their use in ligand design, this thesis also contains work developing carborane-functionalized materials. Due to the charged nature of the carboranes, they are ideal building blocks for ionic liquids. Carboranes possess an array of favorable properties and the goal of the work presented in this thesis is to contribute to a more comprehensive understanding of these unique molecules.

Advances In Organometallic Chemistry Book PDF
✏Book Title : Advances in Organometallic Chemistry
✏Author :
✏Publisher : Academic Press
✏Release Date : 1966-01-01
✏Pages : 477
✏ISBN : 0080580041
✏Available Language : English, Spanish, And French

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✏Advances in Organometallic Chemistry Book Summary : Advances in Organometallic Chemistry

Metal Interactions With Boron Clusters Book PDF
✏Book Title : Metal Interactions with Boron Clusters
✏Author : Russell N. Grimes
✏Publisher : Springer Science & Business Media
✏Release Date : 2013-11-11
✏Pages : 327
✏ISBN : 9781489921543
✏Available Language : English, Spanish, And French

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✏Metal Interactions with Boron Clusters Book Summary : Molecular clusters, in the broad sense that the term is commonly understood, today comprise an enormous class of species extending into virtually every important area of chemistry: "naked" metal clusters, transition metal carbonyl clusters, hydrocarbon cages such as cubane (C H ) and dodecahedrane (C H ), 8 8 20 20 organometallic cluster complexes, enzymes containing Fe S or MoFe S 4 4 3 4 cores, high polymers based on carborane units, and, of course, the many kinds of polyhedral borane species. So large is the area spanned by these diverse classes that any attempt to deal with them comprehensively in one volume would, to say the least, be ambitious-and also premature. We are presently at a stage where intriguing relationships between the various cluster families are becoming apparent (particularly in terms of bonding descriptions), and despite large dif ferences in their chemistry an underlying unity is gradually developing in the field. For example, structural changes occurring in Fe S cores as electrons are 4 4 pumped in and out, in some measure resemble those observed in boranes and carboranes. The cleavage of alkynes via incorporation into carborane cages and subsequent cage rearrangement, a sequence familiar to boron chemists, is a thermodynamically favored process which may be related to the behavior of unsaturated hydrocarbons on metal surfaces; analogies of this sort have drawn attention from theorists and experimentalists.

📒Organometallic Chemistry ✍ Royal Society of Chemistry (Great Britain)

Organometallic Chemistry Book PDF
✏Book Title : Organometallic Chemistry
✏Author : Royal Society of Chemistry (Great Britain)
✏Publisher : Royal Society of Chemistry
✏Release Date : 2007
✏Pages : 332
✏ISBN : 9780854043484
✏Available Language : English, Spanish, And French

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✏Organometallic Chemistry Book Summary : Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry.